Flexible electrode-based voltammetric detection of Y (III) ions in real water samples using an efficient CyDTA complexing strategy

Abstract

The rapid detection of rare earth elements is crucial in various fields, such as materials science, biomedicine, and water quality assessment. However, no studies have reported on the detection of yttrium (Y) using electrochemical sensor-based devices. In this study, we present an innovative method for detecting Y(III) ions in aquatic environments using an electroanalytical detection platform. We have developed a complexation catalytic method that integrates trans-1,2-cyclohexanediaminetetraacetic acid (CyDTA) and silver nanoparticles (Ag NPs), thereby enhancing the adsorption and electrochemical response of Y(III) ions. The modified electrode demonstrates an 18-fold increase in the response signal of the Y(III) reduction peak compared to the bare LIG electrode. To elucidate the electrocatalytic mechanism, we conducted various interface characterization methods and DFT simulations. The Ag-CyDTA/LIG electrode exhibits excellent detection performance, with a broad linear dynamic range of 1 × 10−6 to 0.01 g/L and an exceptionally low detection limit of 0.02 μg/L. Significantly, we successfully employed the electrochemical sensing platform to analyze real water samples from rare earth ore, marking the first report on the voltammetric detection of Y(III) ions in real water samples using a flexible electrode. These findings offer a promising technical solution for the practical detection of Y(III) ions.