Flexible Electrode Based on PES/GO Mixed Matrix Woven Membrane for Efficient Photoelectrochemical Water Splitting Application.

Abstract

We introduced, for the first time, a membrane composed of nanostructured self-polyether sulphone (PES) filled with graphene oxide (GO) applied to photoelectrochemical (PEC) water splitting. This membrane was fabricated through the phase inversion method. A variety of characteristics analysis of GO and its composite with PES including FTIR, XRD, SEM, and optical properties was studied. Its morphology was completely modified from macro voids for bare PES into uniform layers with a random distribution of GO structure which facilitated the movement of electrons between these layers for hydrogen production. The composite membrane photocathode brought a distinct photocurrent generation (5.7 mA/cm2 at 1.6 V vs. RHE). The optimized GO ratio in the membrane was investigated to be PG2 (0.008 wt.% GO). The conversion efficiencies of PEC were assessed for this membrane. Its incident photon-to-current efficiency (IPCE) was calculated to be 14.4% at λ = 390 nm beside the applied bias photon-to-current conversion efficiency (ABPE) that was estimated to be 7.1% at -0.4 V vs. RHE. The stability of the PG2 membrane after six cycles was attributed to high thermal and mechanical stability and excellent ionic conductivity. The number of hydrogen moles was calculated quantitively to be 0.7 mmol h-1 cm-2. Finally, we designed an effective cost membrane with high performance for hydrogen generation.