Flexible cellulose nanofibers/MXene bilayer membrane humidity sensor with a synergistic effect of force and hygroscopic expansion

Abstract

A double layer membrane humidity sensor was designed with a synergistic effect of force and hygroscopic expansion, capitalizing on the high sensitivity demonstrated by MXene material. This sensitivity was achieved through the modulation of resistance change associated with layer spacing of MXene. The double layer structure of sensor was made by vacuum filtration, with an inner layer of MXene for conductivity and an outer layer of cellulose nanofibers (CNF) for moisture absorption, which is rooted in the MXene through the CNFs, similar to the biomimetic structure of hairs rooted in the skin. The synergistic effect of humidity sensitivity is achieved by trapping and dissociating water molecules through the CNF layer generating a change in MXene stress and disrupting the conductive pathway of MXene upon swelling. The CNF/MXene humidity sensor showed a resistance change rate of 117.93 % from 11 % RH to 98 % RH, accompanied by a response time of 319s and a recovery time of 132s. Stable sensing performance is maintained even after 5 times adsorption and desorption cycling, prolonged exposure (7 days) or bending and folding. CNF/MXene bilayer membrane also has good electrical heating performance, reaching about 80 °C at 7V and maintaining stable performance under 5 cycles of heating and 10 min of long heating, respectively. The CNF/MXene membrane humidity sensor can monitor human respiration monitoring, fingertip humidity, pipeline leakage and artifact dehumidification, and combined with the function of electric heating can realize the cycle of dehumidification and humidity monitoring, which has a wide range of application prospects in flexible equipment.