Abstract

Transparent flexible electrodes of metallic nanowire have been spotlighted to develop form factor free electronics for human-machine interfaces. However, state-of-the-art nanowire electrodes have been restricted for flexible application due to multi-stacked morphology with large protrusion and high surface roughness, which generate critical leakage current and device malfunction. Light-material interactions using board-wavelength flash lamps can be a solution for outstanding electrical and morphological properties by inducing a plasmonic welding of flexible metal nanowire. Herein, we propose flash-welded ultraflat electrode networks enabled by nanowire embedding to reduce the protrusion and surface roughness. The nanowire embedded in elastomer presented an ultra-smooth surface of Rq ~ 1.4 nm that prevents leakage current in ultrathin flexible electronics. The excellent electrical properties of ultraflat composite electrode were realized by xenon flash-induced junction welding of metal nanowire. The mechanical stability of flash-welded electrode was confirmed by sheet resistance value under cyclic bending test. Finally, ultraflat silver nanowire networks were utilized in practical application of a leakage current-free flexible optoelectronic device and a triboelectric tactile sensor.

Highlights

  • Light–material interactions using monochromatic lasers and broad-wavelength flash lamps have been spotlighted to improve the electrical properties of flexible metal NW conductors.[33–36] Conventionally, plasmonic metal NW welding was conducted via laser irradiation methods due to its significant capability to precisely adjust processing parameters for heat transfer

  • We report ultraflat AgNW networks with excellent electrical conductivity enabled by AgNW embedding and subsequent flash-induced NW welding

  • Water-soluble PEDOT:PSS was successfully employed as a sacrificial layer to delaminate the embedded AgNW composite from the mother glass substrates, enabling free-standing AgNW/Norland 73 (NOA) transparent flexible electrodes (TFEs) with significantly reduced NW protrusion and surface roughness

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Summary

Introduction

Light–material interactions using monochromatic lasers and broad-wavelength flash lamps have been spotlighted to improve the electrical properties of flexible metal NW conductors.[33–36] Conventionally, plasmonic metal NW welding was conducted via laser irradiation methods due to its significant capability to precisely adjust processing parameters for heat transfer.

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