Fixed bed column evaluation of phosphate adsorption and recovery from aqueous solutions using recycled steel byproducts

Abstract

Excessive phosphorus loading from anthropogenic sources is a major cause of eutrophication of natural waters. Phosphorus is also a non-renewable natural resource that cannot be substituted with other sources. The objective of this study was to determine the feasibility of using recycled steel byproducts to remove and recover phosphate from aqueous solutions. Laboratory fixed bed column experiments were conducted with recycled steel chips of different sizes to evaluate phosphate adsorption characteristics and phosphate recovery efficiencies using alkaline solutions. The results showed that phosphate adsorption onto steel chip filters was characterized by an initial fast breakthrough followed by a stable removal phase. The cumulative phosphate adsorption capacities of the steel chips were 8.43–10.4 mg P/g following 4800 empty bed volumes with a 3 min contact time and an initial concentration of 10 mg P/L. The phosphate adsorption onto steel chips was favored at low flow rates, low pH values, and low organic carbon concentrations. Sodium hydroxide solutions effectively desorbed phosphate from the steel chips. The total phosphate desorption percentages were 58.9%, 64.2%, and 83.4% after 120 empty bed volumes using 0.05 M, 0.10 M, and 0.20 M NaOH solutions, respectively. Steel chips also exhibited high phosphate adsorption and desorption capacities when treating agricultural subsurface drainage water, municipal wastewater, and stormwater runoff. Overall, the results of this study suggest that recycled steel byproducts are efficient and promising low-cost phosphate capturing materials for sustainable phosphorus management.