Abstract
Five new lanthanide coordination polymers, [Ln2(HPA)6(phen)2·solvent] (Ln = Eu, solvent = 4H2O for 1, Ln = Tb, solvent = 2CH3OH for 2, Ln = Pr, solvent = 2H2O for 3, Ln = Nd for 4 and Ln = Er for 5), (HHPA = 3-(4-Hydroxyphenyl)propanoic acid and phen = 1,10-phenanthroline), were successfully synthesized and characterized. The five polymers are isostructural and have 2D supramolecular layered structure. The carboxylic acid ligands adopt bridging, bidentate chelating, and tridentate chelating bridging modes to coordinate with Ln(III) ions. It has been shown that 1 can act as a fluorescent sensor for highly sensitive detection of nitroaromatics and Fe3+. The mixing component of 1/2 = 8:2 not only achieves white-light emission with the CIE coordinate of (0.337, 0.290) upon excitation at 305 nm.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
