Abstract
The title compounds were obtained by oxidative addition of hydrogen halides to suitable [Pt( N,N-chelate) (olefin)] species. The properties of the ligands and of the electrophile which allow the isolation of stable products must meet very strict requirements. The crystal structure of [PtCl(H)(2,9-Me 2-1,1O-phenanthroline) (dimethyl maleate)] was determined by single-crystal X-ray diffraction. Substitution, insertion, and elimination reactions were performed on one hydride complex.
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