Abstract
A five co-ordinate platinum(II) complex containing the water soluble 1,3,5-triaza-7-phosphaadamantane ligand (PTA) [Pt(PTA) 3(I) 2] (1), was characterised in the solid state and aqueous solution. A re-calculation of the Tolman cone angle for the PTA ligand, as well as preliminary equilibrium constants for the formation of 1, is given.
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