Abstract
The Pd-catalyzed reaction of carbanions derived from chromium aminocarbene complexes with allylic acetates and carbonates smoothly affords the corresponding allyl-substituted aminocarbenes. On the contrary, the same reaction of the anion derived from pentacarbonyl[(methoxy)methylcarbene]chromium(0) with cinnamyl acetate affords 5-methoxy-1-phenylhexa-1,5-diene, the product of 1-methoxyethen-1-yl group transfer.
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