Abstract
A new cytotoxic long-chain acetylenic alcohol ( R)-strongylodiol A, originally isolated from an Okinawan marine sponge of the genus Strongylophora, has been synthesized for the first time using commercially available 1,10-decanediol. The key step of this process involves the selective introduction of the ( R)-configuration at C-6 which was achieved by β-elimination of epoxychlorides.
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