Abstract
The first total synthesis of (+)-chrysanthemol (1) has been described starting from (+)-dihydrocarvone (4). The features of our synthesis are the high yield introduction of C3-C4 double bond into eudesmane skeleton and rearrangement of epoxide to allylic alcohol promoted by BF3·OEt2-Bu4NI reagent. In our synthesis, (+)-α-eudesmol (5) has been used as a key intermediate.
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