Abstract
Highly volatile and unstable in the pure form, the 2H-azepine 1 has been synthesized for the first time. This compound is a “spin-off” from work on the chemistry of azepine alkaloids, which occur in the mushroom Chalciporus piperatus. In addition, a bicyclic product of a surprising Diels–Alder reaction forms in the cyclization step.
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More From: Angewandte Chemie International Edition in English
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