First Stage Graphitization of Subcritically Treated White Cast Iron

Abstract

ABSTRACTThe kinetics of first stage graphitization was studied in white cast irons of different compositions. These irons were presubjected to various isothermal anneals at 300–500°C, after being step-quenched from the intercritical (austenite and carbide) region. As a consequence of such pretreatment, the kinetics of post first stage graphitization were substantially accelerated. Both light and scanning electron metallography hive indicated that such acceleration arises due to the creation of vast areas of austenite/carbide interfaces upon cooling to and during subcritical transformations. These interfaces act as favourable nucleation sites for graphite and additionally they provide shorter diffusion paths for carbon. The latter also allows faster growth of graphite nodules. Effects of varying Si and Hn contents of the cast iron were determined. The practical significance of such treatment in providing] faster malleabilization and uniform distribution of graphite nodules is thus evident.