Abstract
The titled tetracyanodiphenoquinodimethane (TCNDQ) derivative was newly designed and prepared as a novel component for highly conductive organic materials. Introduction of 1,2,5-thiadiazole rings into the TCNDQ skeleton leads to large stabilization in the neutral state. X-ray analysis has revealed their structural details which suggest that interatomic interactions (CH…N, S…N) play an important role in determining the molecular and crystal structure. The novel electron acceptor shows strong electron affinity comparable with that of TCNQ, and gave highly conductive charge-transfer (CT) complexes and an anion radical salt.
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