Abstract
The syntheses and characterizations of homoleptic silver(I) carbene complexes of the type LAgCl ( 3) and [L 2Ag] + 2[Pd 2Cl 6] 2− ( 4) (L=dimesityltetrahydropyrimid-2-ylidene) are described. 3 was obtained by reaction of the corresponding tetrahydropyrimidinium salt with silver(I) oxide. Subsequent reaction of 3 with Pd(CH 3CN) 2Cl 2 afforded complex 4. The crystal structure of 3 has been determined to be a monomer in the solid state. The 13C NMR spectra of both 3 and 4 exhibit 13C– 107,109Ag coupling in solution. Furthermore, both compounds show a downfield shift of the carbene carbon of about 20 ppm to about 205 ppm in the 13C NMR compared to five-membered ring silver(I) carbene complexes. Unlike other silver–carbene complexes, 3 does not undergo ligand exchange and can thus not be used for carbene transfer to other metals.
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