Abstract
AbstractConformations and some electronic properties of the 2,2′‐bisindolyls 6 were calculated for the prediction of probable Diels‐Alder reactivity, in analogy to previous work on 2‐vinylindoles. First reactions with dienophiles revealed that compounds 6 did not participate in [4 + 2]cycloadditions but rather underwent simple electrophilic substitutions at the enamine function with, above all, some heterodienophiles.
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