Abstract
Using inputs from first-principles calculations, an ab initio model was employed to investigate crystal orientation dependent corrosion behavior of BCC iron. Results showed that the sequence of corrosion susceptibility of BCC Fe surfaces is in the order of (100) > (111) > (211) > (310) > (110). The higher corrosion current on (100) surface suggests that cathodic hydrogen evolution may largely determine the corrosion reactions under acidic environment. The predicted corrosion potential and current for lower index planes are in general agreement with available experiment. The model was further applied to study alloying effects with results validated via weight loss analysis of alloyant fabricated by arc melting.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.