Abstract
A new band system has been recorded photoelectrically at low resolution from the reaction of discharged helium with AsCl 3 at total pressures near 3 Torr. Fifty-nine head positions have been assigned to a 2Π → X 2Π system of As 35Cl + and As 37Cl +. Estimated vibrational constants (cm −1) for As 35Cl + from a least squares fit are as follows: T′ e = 25435, Δ G′( 1 2 ) = 242.4, ω″ e = 527.7, ω″ ex ″ e = 1.739, Δ A = z.snfc; A′ e − A″ e = 1386.3.
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More From: Spectrochimica Acta Part A: Molecular Spectroscopy
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