Abstract
The binuclear, triple decker sandwich compound [(η 5-NC 4Me 4)Co] 2(C 2Et 2B 3H 3) has a C 2Et 2B 3H 3 ring at the center stabilizing a π-pyrrolyl-Co group on either side. The compound is the first π-bond triple decker pyrrolyl complex and the structure is the first of a π pyrrolyl-metal complex. Crystal data: monoclinic, space group P2 1/ c, Z=4, a=14.973(3); b=9.029(2); c=18.659(5) Å; β=106.38(4)°. R=3.8% for 1387 reflections.
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