Abstract

We present a geochemical dataset acquired during continual sampling over 7 months (bi-weekly) and 4 weeks (every 8 h) in the Neuwied Basin, a part of the East Eifel Volcanic Field (EEVF, Germany). We used a combination of geochemical, geophysical, and statistical methods to describe and identify potential causal processes underlying the correlations of degassing patterns of CO2, He, Rn, and tectonic processes in three investigated mineral springs (Nette, Kärlich and Kobern). We provide for the first time, temporal analyses of periodic degassing patterns (1 day and 2–6 days) in springs. The temporal fluctuations in cyclic behavior of 4–5 days that we recorded had not been observed previously but may be attributed to a fundamental change in either gas source processes, subsequent gas transport to the surface, or the influence of volcano–tectonic earthquakes. Periods observed at 10 and 15 days may be related to discharge pulses of magma in the same periodic rhythm. We report the potential hint that deep low-frequency (DLF) earthquakes might actively modulate degassing. Temporal analyses of the CO2–He and CO2–Rn couples indicate that all springs are interlinked by previously unknown fault systems. The volcanic activity in the EEVF is dormant but not extinct. To understand and monitor its magmatic and degassing systems in relation to new developments in DLF-earthquakes and magmatic recharging processes and to identify seasonal variation in gas flux, we recommend continual monitoring of geogenic gases in all available springs taken at short temporal intervals.

Highlights

  • Continental rifts and their related volcanic systems may be important contributors to deep, diffuse carbon fluxes due to intrusion and melting of metasomatized, volatile-enriched lithosphere and elevated magmatic fluxes

  • To better understand geogenic gas emissions, their rhythms, and potential changes during episodes of seismic unrest in the Eifel Volcanic field (EEVF), we provide for the first time fine-scale data for three mineral springs: (a) Flöcksmühle in the Nette river near Ochtendung; (b) Waldmühle in Mülheim-Kärlich; and (c) ‘Kobern’ in Kobern-Gondorf in relation to parallel investigated soil gas analyses at the Goloring study site near Koblenz (≈6 km from the investigated mineral springs) that allow for periodic analyses

  • CO2 was the major component of the measured gases in the mineral springs

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Summary

Introduction

Continental rifts and their related volcanic systems may be important contributors to deep, diffuse carbon fluxes due to intrusion and melting of metasomatized, volatile-enriched lithosphere and elevated magmatic fluxes. Burton [2] and Mörner and Etiope [3] point out that slow, passive degassing of volatiles over long periods of time is a more important process than volcanic eruptions of short duration. Such passive release of volatiles and their variations in composition at the. Earth’s surface represent the only indicator of a degassing magma source at depth [4]. During their migration towards the surface, these gases may contain components from three reservoirs: Mantle, Geosciences 2019, 9, 189; doi:10.3390/geosciences9040189 www.mdpi.com/journal/geosciences

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