Abstract
The rotational structure in three fundamental bands ν3, ν5, and ν6of13CHD3has been analyzed. As this study evidently is the first high-resolution investigation on the spectrum of this molecule, the determination of the ground state rotational constants was the necessary first step. The ν5band (1290.536 cm−1) could be treated as an isolated band whereas it was necessary to analyze the bands ν3(994.713 cm−1) and ν6(1030.243 cm−1) simultaneously because of very strong interactions. The total number of assigned lines was 1116. The spectral region 850–1530 cm−1was measured on a Fourier transform spectrometer and the13C species was in natural abundance in CHD3.
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