Abstract
Glycals undergo smooth carbon-Ferrier rearrangement with isocyanides in the presence of a catalytic amount of FeCl 3 under mild reaction conditions to provide C-glycosyl amides in good yields with high α-selectivity. The use of FeCl 3 makes this method simple, convenient and cost-effective. This is the first report on carbon-Ferrier rearrangement using isonitriles as nucleophiles.
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