Abstract

Abstract Self-assembly of AgClO 4 with bis(4-pyridyl)cyclotetramethylsilane (L) produces a 4-fold interpenetrating 3D coordination polymeric framework consisting of [Ag 5 (L) 7 (CH 3 CN) 2 ](ClO 4 ) 5 ∙2CH 3 CN ( 1 ). The topological analysis indicates that the compound is the first example of a binodal 3,3-connected (8 2 ∙10) 2 - ete net topology. Its thermal behavior and photoluminescent properties have been investigated.

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