Abstract
1-(4-Methoxyphenyltelluro)-2-[3-(6 methyl-2 pyridyl)propoxy]ethane ( L 1 ) and its complexes [MCl 2( L 1 )] 2 (M = Pd or Pt) have been synthesized. The single crystal X-ray diffraction of [PtCl 2( L 1 )] 2 · 2CHCl 3 shows a bimetallic complex of platinum(II) containing a 20-membered metallomacrocycle ring, which remains stable in solution as shown by molecular weight and conductance measurements. The Pt–Te and Pt–N bond lengths are 2.5409(3) and 2.087(5) Å, respectively. The protons of CH 2 linked to Te show a deshielding > 1 ppm on the formation of the two complexes.
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