Abstract
Chlorobis(cyclopentadienyl)[1-(1,3,2-dioxaborinane-2-yl)hexyl]zirconium(IV)2, fully characterized by X-ray, 1H–1H double-quantum-filtered COSY and 13C-1H heteronuclear chemical shift correlation NMR studies, IR and elemental analysis, reacts selectively with electrophilic reagents, N-bromo- and N-chlorosuccinimide and bromine to give α-halobronic esters; it also polymerizes styrene without the aid of a co-catalyst.
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