First catalytic application of metal complexes of porpholactone and dihydroxychlorin in the sulfoxidation reaction

Rahmatollah Rahimi,Mahmood Azizpoor Fard,Hamid Reza Khavasi,Alireza Azhdari Tehrani,Bahareh Mir Mohammad Sadegh

doi:10.1016/j.catcom.2009.09.022

First catalytic application of metal complexes of porpholactone and dihydroxychlorin in the sulfoxidation reaction

Rahmatollah Rahimi, Mahmood Azizpoor Fard + Show 3 more

https://doi.org/10.1016/j.catcom.2009.09.022

Copy DOI

Journal: Catalysis Communications	Publication Date: Oct 6, 2009
Citations: 28

Affiliation: Iran University of Science and Technology, Shahid Beheshti University

#Effect Of Catalyst Concentration #Sulfide Substrates + Show 8 more

Abstract
Full-Text PDF
Similar Papers

Abstract

Abstract Iron and manganese complexes meso-tetraphenylporpholactone, MTPPLX, and meso-tetraphenyl-2,3-dihydroxy-2,3-chlorin, MTPP(OH)2X (X = Cl and (CH3COO)), are efficient catalysts for selective oxidation of sulfides with hydrogen peroxide. The effect of catalyst concentration on the conversion, selectivity and yield of products were studied. The results show that iron and manganese porpholactones and chlorins are a slightly better catalyst than TPP analogues for most sulfide substrates.

Full Text