Fire-resistant and low-temperature self-healing bio-based hydrogel electrolytes based on peach gum polysaccharide/sisal nanofibers for flexible supercapacitors

Abstract

The introduction of flame retardancy and low-temperature self-healing capacities in hydrogel electrolytes are crucial for promoting the cycle stability and durability of the flexible supercapacitors in extreme environments. Herein, biomass-based dual-network hydrogel electrolyte (named PSBGL), was synthesized with borax crosslinked peach gum polysaccharide/sisal nanofibers composite, and its application in flexible supercapacitors was also investigated in detail. The dynamic cross-linking of the dual-network endows the PSBGL with excellent self-healing performance, enabling ultrafast self-healing within seconds at both room temperature and extreme low temperatures. The PSBGL bio-based hydrogel electrolyte can maintain the integrity of the carbon layer structure with limiting oxygen index of 56 % after 60 s of combustion under a flame gun. Additionally, the PSBGL exhibits high ionic conductivity (30.12 mS cm−1), good tensile strength (1.78 MPa), and robust adhesion to electrodes (1.15 MPa). The assembled supercapacitors demonstrate a high specific capacitance of 187.8 F g−1 at 0.5 A g−1, with 95.9 % capacitance retention rate after 10,000 cycles at room temperature. Importantly, even under extreme temperatures of 60 °C and −35 °C, the supercapacitors can also maintain high capacitance retention rates of 90.1 % and 86.5 % after 10,000 cycles. This work fills the gap between biomaterial design and high-performance flexible supercapacitors.