Abstract

Recent developments of intumescent fire-protective coatings used in steel buildings are important to ensure the structural integrity and safe evacuation of occupants during fire accidents. Flame-retardant intumescent coating applied to structural steel could delay the spread of fire and heat propagation across spaces and structures in minimizing fire risks. This research focuses on formulating a green intumescent coating utilized the BioAsh, a by-product derived from natural rubberwood (hardwood) biomass combustion as the natural substitute of mineral fillers in the intumescent coating. Fire resistance, chemical, physical and mechanical properties of all samples were examined via Bunsen burner, thermogravimetric analysis (TGA), carbolite furnace, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), Fourier transform infrared (FTIR), freeze–thaw cycle, static immersion and Instron pull-off adhesion test. Sample BioAsh intumescent coating (BAIC) 4-7 incorporated with 3.5 wt.% BioAsh exhibited the best performances in terms of fire resistance (112.5 °C for an hour under the Bunsen burner test), thermal stability (residual weight of 29.48 wt.% at 1000 °C in TGA test), adhesion strength (1.73 MPa under Instron pull-off adhesion test), water resistance (water absorption rate of 8.72%) and freeze–thaw durability (no crack, blister and color change) as compared to other samples. These results reveal that an appropriate amount of renewable BioAsh incorporated as natural mineral fillers into the intumescent coating could lead to better fire resistance and mechanical properties for the steel structures.

Highlights

  • The fire resistance of materials is one of the key fire safety measures in building design and the construction industry—it must comply with BS 476

  • BioAsh was used as the natural substitute of flame-retardant mineral fillers in the Intumescent coating (IC) formulations due to it consisting of a group of high thermal stability elements [37]

  • BioAsh intumescent coating (BAIC) samples were formulated in the laboratory

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Summary

Introduction

The fire resistance of materials is one of the key fire safety measures in building design and the construction industry—it must comply with BS 476. Advanced studies have been conducted to explore the potential of various aviculture waste (eggshell), agriculture waste (rice husk ash), aquaculture waste (clam shell) and crop-based biomass (ginger powder and coffee husk) to produce eco-compatible IC formulations with enhanced fire-resistant performance [48,51,52,53]. These studies of using natural-based fillers in the IC reported various improvements in the fire-resistant properties. Performances of fire resistance, thermal, physical, chemical and mechanical properties of green intumescent flame-retarded coating incorporated with BioAsh were evaluated and examined

Raw Materials and Intumescent Coating Samples Preparation
Fire Resistance Test
Carbolite Furnace Test
Freeze–Thaw Cycle Test
Static Immersion Test
Instron Pull-off Adhesion Test
Fire Resistance
Char Thickness
Thermogravimetric Analysis
Derivative thermogravimetric analysis
BAICCaCO
POtime
6: Fire test willtest subject future
Elemental Composition Analysis of BioAsh and Coating Samples
FTIR Analysis
10. Infrared
Freeze–Thaw Cycle
Static Immersion
Findings
Pull-off
Full Text
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