Abstract
Abstract Curvilinear internal coordinates are considered in terms of cartesian displacements in a molecule-fixed basis determined by the Eckart-Sayvetz conditions. The latter are interpreted as a set of restrictions on the metrics of the space and define cartesian displacements of “pure” vibrational character expanded to any order in terms of internal coordinates. Explicit expressions for expansion coefficients are given as a function of contravariant components of the metric tensor taken from existing table. A compact notation is proposed for anharmonic force constants, expansion coefficients of redundancies and coupling terms of the rotation—vibration hamiltonian.
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