Finite-temperature properties of the triangular latticet−Jmodel and applications toNaxCoO2

Abstract

We present a finite temperature ($T$) study of the t-J model on the two-dimensional triangular lattice for the negative hopping $t$, as relevant for the electron-doped Na$_x$CoO$_2$ (NCO). To understand several aspects of this system, we study the $T$-dependent chemical potential, specific heat, magnetic susceptibility, and the dynamic Hall-coefficient across the entire doping range. We show systematically, how this simplest model for strongly correlated electrons describes a crossover as function of doping ($x$) from a Pauli-like weakly spin-correlated metal close to the band-limit (density $n=2$) to the Curie-Weiss metallic phase ($1.5<n<1.75$) with pronounced anti-ferromagnetic (AFM) correlations at low temperatures and Curie-Weiss type behavior in the high-temperature regime. Upon further reduction of the doping, a new energy scale, dominated by spin-interactions ($J$) emerges (apparent both in specific heat and susceptibility) and we identify an effective interaction $J_{eff}(x)$, valid across the entire doping range. This is distinct from Anderson's formula, as we choose here $t<0$, hence the opposite sign of the usual Nagaoka-ferromagnetic situation. This expression includes the subtle effect of weak kinetic AFM - as encountered in the infinitely correlated situation ($U=\infty$). By explicit computation of the Kubo-formulae, we address the question of practical relevance of the high-frequency expression for the Hall coefficient $R_H^*$. We hope to clarify some open questions concerning the applicability of the t-J model to real experimental situations through this study.