Abstract

In this work finite element simulations are used based on the micro structure of polymers in order to transfer the information of the micro level to the macro level. The microscopic structure of polymers is characterized by a three-dimensional network consisting of randomly oriented chain-like macromolecules linked together at certain points. Different techniques are used to simulate the rubber-like material behaviour of such networks. These techniques range from molecular dynamics to the finite element method.The proposed approach is based on a so-called unit cell. This unit cell consists of one tetrahedral element and six truss elements. To each edge of the tetrahedron one truss element is attached which models the force-stretch behaviour of a bundle of polymer chains. The proposed method provides the possibility to observe how changes at the microscopic level influence the macroscopic material behaviour. Such observations were carried out in [1]. The main focus of this work is the validation of the proposed approach. Therefore the model is compared to different experimental data and other statistically-based network models describing rubber-like material behaviour.

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