Fine-tuning morphology via oligo(ethylene oxide) side chain engineering for squaraine-based organic solar cells

Abstract

Two squaraine dyes (SQs), USQ-O bearing oligo(ethylene oxide) (OE) chain, and USQ-C bearing alkyl chain, were synthesized. The influence of OE side chain on photovoltaic performances was systematically investigated. USQ-C and USQ-O show similar absorption spectra in dilute solutions, energy levels, charge mobility and the molecular electrostatic potential (ESP) on the conjugated skeleton. However, USQ-O exhibits hypsochromic absorption band compared to that of USQ-C in the film, and the distribution of positive and negative alternating ESP on the OE side chain. Significantly different electrostatic interactions and multiple hydrogen bonds among OE side chains could greatly affect the behaviors of intermolecular interactions, and, in turn, influence the photophysical properties of pristine/blend films and the miscibility with PC71BM acceptor. USQ-O-based devices exhibit higher short circuit current than that of USQ-C-based (13.94 vs 12.36 mA cm−2), which could be principally put down to the effective improvement of the blending morphology. These results indicate that simply substituted alkyl chain by OE chain for SQ is an effective strategy for optimizing morphology.