Abstract
The fine structure of the NO C 2Π → A 2Σ+ (0-0) and D 2Σ+ → A 2Σ+ (0-0) bands have been resolved with a high resolution Fourier Transform Spectrometer. The interactions of the three electronic states C 2Π, D 2Σ+, B 2Π have been carefully analysed. Homogeneous and heterogeneous perturbations were reduced taking account the influence of the B 2Π (ν = 7, 8, 9, 10) vibrational levels on the levels C 2Π (ν = 0) and D 2Σ+ (ν = 0). Accurate energy values are derived for the low lying rotational levels of the C 2Π (ν = 0) level.
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