Final state core level binding energy shifts in binary alloys

Abstract

The final state or relaxation contribution to core level binding energy shift is calculated for some noble metal/transition metal alloy systems, using the pseudopotential linear response method developed previously for pure metals. The core hole perturbation is described by an ab-initio pseudopotential. A basic parameter of the method is the homogeneous electron gas density for which, in the present case, a mean value between those corresponding to each pure metal is adopted. The final state contribution is generally found to be important and sometimes dominant. From the experimental core level shifts and the calculated final state shifts, some considerations about initial state contribution are given.