Film-like bacterial cellulose/cyclodextrin oligomer composites with controllable structure for the removal of various persistent organic pollutants from water

Abstract

The adsorptive removal of persistent organic pollutants (POPs) is reckoned as a simple, convenient, and practical technology, especially in decentralized systems and remote areas. For this purpose, it is important to design new adsorbents, with controllable structure and convenient shape, for the highly efficient removal of POPs. In this study, we describe a strategy for film-like water purifier, prepared by loading cyclodextrin (CD) oligomer onto the ultrafine nanofibers of 3D bacterial cellulose. The optimum product exhibits remarkable removal ability toward various target pollutants such as phenol, bisphenol A (BPA), glyphosate and 2,4-Dichlorophenol (2,4-DCP), with capacities higher than most adsorbents including porous carbon based materials reported previously. Moreover, our sample demonstrated stable adsorption ability over a broad pH range and under more complex water conditions, and more importantly excellent reusability. A rough cost analysis highlights the commercial potential of our sample. We reckon our study provides new insight for the design of adsorbent with high yet stable adsorption ability and controllable structure. Furthermore, the product can be used to treat actual sewage with its convenient film-like shape and excellent performance, which improves its potential in complex systems and large-scale applications.