Film forming behaviour of oil soluble polyalkylene glycols

Abstract

Purpose – The purpose of this paper was to examine the film-forming behaviour of simple compositions of polyalphaolefin (PAO) containing an oil-soluble polyalkylene glycol (OSP) alone, a zinc dialkyl dithiophosphate (ZDDP) alone and then combinations of an OSP and ZDDP. Design/methodology/approach – A Mini-Traction Machine with Spacer Layer Imaging technology was used to evaluate friction and film formation under a specific contact pressure, temperature and slide-to-roll ratio. Electrical contact resistance measurements were used to follow surface film formation. Findings – The inclusion of an OSP to a PAO showed evidence of friction-reducing behaviour with low friction values over the rubbing cycle but no significant tribo-film build up. When a ZDDP (1 per cent) is added to the PAO, a thick tribo-film forms of about 100 nm. Addition of an OSP (10 per cent) shows this film still forms despite the OSP being a polar and surface-active additive. Research limitations/implications – The study was conducted under a narrow range of test conditions (e.g. temperature and contact pressure), and future work will focus on friction and film formation across a broader set of conditions. Practical implications – Despite OSPs being polar and surface-active, they do not interfere with the ZDDP in forming an anti-wear film in a PAO and, therefore, their inherent properties of good deposit control could enhance the performance of modern lubricants. Originality/value – OSPs offer promising benefits as friction reducers in PAOs. The research also suggests that OSPs do not negate the formation of ZDDP anti-wear tribo-films when in combination in a PAO.