Film electrode by incorporating polypyrrole/carbon black into cross-linked binders of chitosan/cationic polyacrylamide for selective chloride extraction in wastewater

Abstract

Water-based binders are usually free of volatile organic compounds and hazardous reagents, which reduces the impact on the environment, and research and development of water-based binders has been progressing in recent years. In order to increase the adhesion and mechanical properties of the composite film electrode, lower the resistance to ion transfer, and improve the adsorption capacity of Cl−, a unique cross-linked aqueous binder composite film electrode was created. The film electrode for the electrochemically switched ion exchange (ESIX) system's Cl− adsorption and desorption was successfully prepared by incorporating polypyrrole (PPy-Cl)/carbon black (C) into chemically cross-linked chitosan (CS) and cationic polyacrylamide (CPAM) by glutaraldehyde (GA). The film electrode of formulated PPy-Cl/C/CS-c-CPAM had advantages over the film electrode of PPy-Cl/C/PVDF (polyvinylidene fluoride). The PPy-Cl/C/CS-c-CPAM film electrode had 33.56 mg g−1 adsorption capacity when operated at 0.8 V for the oxidation potential, high selectivity, short adsorption time, and excellent adhesions. CS-c-CPAM composite binders provide a new direction for realizing the superior performance of the film electrodes.