Novel approach: Simultaneous application of ionic liquid doped polymer electrolyte in supercapacitor and dye-sensitized solar cells

Abstract

The present study reports the synthesis, characterization, and application as energy devices of an ionic liquid blended polymer electrolyte film in which the host polymer polyvinyl alcohol (PVA) is mixed with low viscosity ionic liquid (IL) 1-ethyl-3-methylimidazolium thiocyanate. Various characterization tools have been used further to elaborate electrical, structural, and photoelectrochemical properties. X-ray diffraction (XRD) and polarized optical microscope (POM) affirm the reduction of crystallinity of polymer, while Fourier transform infrared spectroscopy (FTIR) shows complexation and composite nature. Electrochemical impedance spectroscopy shows an enhancement in ionic conductivity by IL doping, where the highest conductivity is achieved at 60 wt% of IL concentration with a conductivity value of 6.21 × 10⁻⁴ S/cm. The ionic transference number (tion) and electrochemical stability measurement show the film's predominantly ionic nature and a reasonable stability window. Using maximum conducting film sandwiched between electrodes, we have successfully fabricated two devices, i.e., an electrical double-layer capacitor (EDLC) and a dye-sensitized solar cell (DSSC). The fabricated EDLC capacitor shows a specific capacitance of 125 F/g, while DSSC shows an efficiency of 1.1 % at one sun condition.