Field-Induced Microwave Absorption in Ni Ferrite Nanoparticles

Abstract

Ferrite nanoparticles are in the last years a matter of strong interest due to the fact that nanoscale materials possess size-dependent optical, electronic, magnetic, thermal, mechanical, and chemical properties that are comparable to or superior to those of bulk material counterparts, as well as its potential applications in sensors or microwave devices. Nickel ferrites, which are well-known technological materials in various electronic devices, were prepared in the form of nanoparticles by a modified sol-gel technique employing coconut oil, and then annealed at different temperatures in the 400 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">°</sup> C-1200 <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">°</sup> C range. This route of preparation has been revealed to be one efficient and cheap technique to obain high-quality nickel ferrite nanosized powder. Sample particle sizes obtained with X-ray diffraction data and Scherrer's formula lie in 13-138 nm, with increased size with annealing temperature. Magnetic field-induced microwave absorption in nanoscale ferrites is a recent an active area of research, in order to characterize and explore potential novel applications. In the present work, microwave magnetoabsorption data of the annealed nickel ferrite nanoparticles are presented. These data have been obtained with a system developped in our laboratory, based on a network analyzer that operates in the frequency range 0-8.5 GHz. We can observe a resonance peak with applied fields of up to 400 mT. The results are interpreted on the basis of ferromagnetic resonance theory.