Abstract

Integral energy distributions of field emitted singly and doubly charged metal ions (Cu +, Be +, Be ++, Ni +, Ni ++) are measured. Appearance Potentials AP n ( n = 1, 2) are derived from the onset of the energy distribution. With low emitter temperatures (≲300 K) experimental AP n values coincide with values calculated from the image hump model of field evaporation, both for singly and doubly charged species. With high emitter temperatures (≳900 K) AP 1 values of singly charged ions reflect the first ionization potential I 1 of gaseous metal atoms. A few ions display AP 1 values down to 5 eV below I 1. This is explained by field ionization of electron excited atoms.

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