Field Evaluation of High Voltage Electron Beam Technology for Treating VOC-Contaminated Groundwater. Part I: VOC Removals and Treatment Costs

Abstract

AbstractAs part of the Superfund Innovative Technology Evaluation program, the U.S. Environmental Protection Agency evaluated the High Voltage Environmental Applications, Inc. (HVEA), electron beam (E-beam) technology at the U.S. Department of Energy Savannah River Site (SRS) in Aiken, South Carolina. This technology irradiates water with a beam of high-energy electrons, causing the formation of three primary transient reactive species: aqueous electrons, hydroxyl radicals, and hydrogen radicals. Target organic compounds are either mineralized or broken down into low molecular weight organic compounds, primarily by these species. The E-beam system used for the evaluation is housed in an 8- by 48-foot trailer and is rated for a maximum flow rate of 50 gpm. During two different periods totaling 3 weeks in September and November 1994, about 70,000 gallons of SRS M-area groundwater contaminated with volatile organic compounds (VOCs) was treated with the E-beam system. The highest removal efficiencies (REs) observed for unsaturated chlorinated VOCs in groundwater - trichloroethene (TCE), tetrachloroethene (PCE), and cis-1,2-dichloroethene (1,2-DCE) - were >99, 99, and > 91%, respectively. REs ranged from 68 to > 98% for 1,1,1-trichloroethane (1,1,1-TCA), 1,2-dichloroethane (1,2-DCA), chloroform, and carbon tetrachloride (CCl