Field assisted sintering of Ta–Al2O3 composite materials and investigation of electrical conductivity

Abstract

Ta–Al2O3 composite samples with different compositions are prepared using Field Assisted Sintering Technique (FAST). Two different alumina powders are used to investigate the influence of the starting powders particle size on the microstructural features and the resulting electrical conductivity of the prepared composite materials. Percolation threshold of the two material systems is influenced by the metal fraction, as well as the alumina particle size of the starting powder. The percolation threshold for the fine- and the coarse-grained alumina is found to be at 15 vol.-% Ta and 7.5 vol.-% Ta, respectively. Microstructural investigations show significant differences in terms of particle shape of both, Ta and Al2O3 after sintering, most likely being the reason for the different percolation thresholds of the investigated materials. Anisotropy effects resulting from the processing using FAST and the influence on electrical properties are also shown.