Abstract
The creation of high surface area and effective active sites is the key problem for the synthesis of high-performance porous carbon materials. In this work, polyacrylonitrile-coated fibrous silica (F-SiO2@PAN) microspheres were prepared by in situ polymerization of acrylonitrile on fibrous mesoporous silica microspheres induced by γ-ray radiation. After F-SiO2@PAN microspheres were carbonized and etched with hydrofluoric acid, uniform fibrous N-doped porous carbon (FNC) microspheres with an average size of 286nm and a molar ratio of C/N of 5.2 were successfully prepared. As revealed by TEM, SEM, and N2 adsorption-desorption isotherms analysis, FNC microspheres have a hierarchal micro-macroporous structure with a particular high surface area of 554.5m2/g. The FNC microspheres also exhibit a good water dispersibility and an excellent adsorption ability to rhodamine B in water. The equilibrium adsorption capacity of FNC microspheres could reach 95.4mg/g, which is 1.6 times as that of the primary silica template microspheres. The adsorption kinetics and thermodynamics of FNC microspheres are in accord with the pseudo-second-order kinetic equation and Freundlich isotherm model, respectively. This work provides a facile synthesis method for novel N-doped hierarchical micro-macroporous carbon microsphere as a potential high-performance adsorbent material.
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