Abstract

Ferryl and Ferrate Species: Mössbauer Spectroscopy Investigation

Highlights

  • I RON is an earth abundant element that occurs in +2 and +3 oxidation states, Fe(II) and Fe(III), in the natural environment

  • The Fe(II) centers in the enzymes can perform different two-electron oxidation reactions. These high-valent iron species may be participating in other reactions including epoxidation, decarboxylation, and cyclization.[6,10]

  • This paper presents some examples on the application of Mössbauer spectroscopy to characterize ferryl and ferrate species

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Summary

Introduction

I RON is an earth abundant element that occurs in +2 and +3 oxidation states, Fe(II) and Fe(III), in the natural environment. Studies on the synthesis of iron-nitro compounds having valence states of +4, +5, and +6 have been reported.[1,11,13] Figure 4 shows the example of the scheme in which different high-valent species have been demonstrated.

Results
Conclusion

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