Abstract

Spherical zinc particles ranging in average size from 275 to 760 nm and covered with platelike zinc oxide particles on the order of 10 nm in size have been prepared by levitation-jet aerosol synthesis through condensation of zinc vapor in an inert-gas flow. The nanoparticles have been characterized by transmission electron microscopy, X-ray diffraction, BET measurements, and vibrating-sample magnetometry. The results indicate that the observed ferromagnetic ordering is due to changes in unit-cell volume on the surface of the nanoparticles. High-temperature magnetization data demonstrate that the ferromagnetic ordering of the nanoparticles persists up to 750 K.

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