Abstract

Diluted magnetic semiconductor (DMS) and layered material black phosphorus (BP) are two kinds of important materials. In this manuscript, it was reported on the observation of ferromagnetism in Ti-doped BP synthesized by high pressure method. Clear hysteresis loops were observed at room temperature. The Curie temperature was deduced to be 130-140 K. Transport studies showed us temperature dependent positive-to-negative magnetoresistance (MR) transition with the 40% MR effect at 30 K under the magnetic field of 50 kOe.

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