Abstract
We report the appearance of ferroelectricity below ${T}_{S}=18$ K, at which short-ranged spiral spin orders, suggesting that ${\mathrm{MnCr}}_{2}{\mathrm{O}}_{4}$ is an improper multiferroic material. Linear heat capacity data and zero-field-cooled memory effect verify reentrant spin-glass-like state below ${T}_{S}$. Synchrotron x-ray diffraction studies confirm significant magnetoelastic coupling at long-range ferrimagnetic order (${T}_{N}=42$ K) and at ${T}_{S}$. We argue that the release of topological spin frustration, produced due to pyrochlore structure of Cr sublattice, is manifested through the significant magnetoelastic effect at ${T}_{N}$ and ${T}_{S}$ and holds the key for spiral spin order driven ferroelectricity in ${\mathrm{MnCr}}_{2}{\mathrm{O}}_{4}$.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.