Ferroelectric-Dielectric Solid Solution and Composites for Tunable Microwave Application

Abstract

Electric field tunable ferroelectric materials have attracted extensive attention in recent years due to their potential applications for tunable microwave device such as tunable filters, phased array antennas, delay lines and phase shifters (Maiti et al. 2007a; Rao et al. 1999; Romanofsky et al. 2000; Varadan et al 1992.; Zhi et al. 2002). Ba1-xSrxTiO3 and BaZrxTi1−xO3 have received the most attention due to their intrinsic high dielectric tunability. However, the high inherent materials loss and high dielectric constant has restricted its application in tunable microwave device. Various methods have been investigated to lower the dielectric constant and loss tangent of pure ferroelectrics. Forming ferroelectric-dielectric composite is an efficient method to reduce material dielectric constant, loss tangent and maintain tunability at a sufficiently high level. For binary ferroelectric-dielectric composite (such as BST+MgO) (Chang & Sengupta 2002; Sengupta & Sengupta 1999), with the increase of dielectrics content, the dielectric constant and tunability of composites decrease. In order to decrease the dielectric constant of binary composite, it is necessary to increase the content of linear dielectric, and the tunability will decrease inevitably due to ferroelectric dilution. Replacing one dielectric by the combination of dielectrics with different dielectric constants and forming ternary ferroelectric-dielectric composite can decrease the dielectric constant of composite and maintain or even increase the tunability. This is beneficial for tunable application. The Ba0.6Sr0.4TiO3-Mg2SiO4-MgO and BaZr0.2Ti0.8O3-Mg2SiO4-MgO composites exhibited relatively high tunability in combination with reduced dielectric permittivity and reduced loss tangent (He et al. 2010, 2011). With the increase of Mg2SiO4 content and the decrease of MgO content in Ba0.6Sr0.4TiO3-Mg2SiO4-MgO composite, the dielectric constant decrease and the tunability remain almost unchanged. For BaZr0.2Ti0.8O3-Mg2SiO4-MgO composite, an anomalous relation between dielectric constant and tunability was observed: with the increase of Mg2SiO4 content (>30 wt%), the dielectric constant of composite decreases and the tunability increases. The anomalous increased tunability can be attributed to redistribution of the electric field. Ba1-xSrxTiO3-Mg2TiO4-MgO can also form ferroelectric (Ba1-xSrxTiO3)-dielectric (Mg2TiO4-MgO) ternary composite and the dielectric constant can be decreased. With the increase of Mg2TiO4 content and the decrease of MgO content, the tunability of Ba1-xSrxTiO3Mg2TiO4-MgO composite increase. The multiple-phase composites might complicate method to effectively deposit films, particularly if the dielectrics and ferroelectric are not compatible for simultaneous deposition or simultaneous adhesion with a substrate or with