Abstract

A series of novel hybride ferrocene carborane derivatives containing allyl functionalities at the carborane carbon atoms were firstly synthesized in a good yield providing their potential applications in various fields of material science. Synthesized compounds were characterized using various spectroscopic techniques like IR, ESI-MS, 1H and 11B NMR data. Some compounds were investigated by cyclic voltammetry. The total charge density around each atom was calculated for 1-allyl-9-ferrocenylmethyl-m-carborane. Particular attention has been focused on the analysis of 1H NMR spectra of diallyl-substituted ferrocene carboranes which made it possible to discover the migration of the double bond in allyl substituent and the formation along with diallyl derivative of the corresponding allylpropenyl isomer compounds.

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