Abstract
AbstractTerminal redox‐active ferrocenyl groups were introduced into the redox‐active p‐phenylenediamine bridging spacer, which can be oxidized to the p‐quinonediimine, to provide a redox‐switching system with electronic communication between the ferrocenyl groups through the redox‐active π‐conjugated bridging spacer. The communication was controlled by redox interconversion between the p‐phenylenediamine and p‐quinonediimine spacers. Furthermore, two palladium complexes were demonstrated to be introduced to the oxidized quinonediimine moiety, affording the multimetallic complex, in which the complexed quinonediimine serves as an electron sink. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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